9,9'-Spirobifluorene Based MOFs: Synthesis, Structure, Catalytic Properties
نویسندگان
چکیده
منابع مشابه
Crystalline metal-organic frameworks (MOFs): synthesis, structure and function.
Metal-organic frameworks (MOFs) are a class of hybrid network supramolecular solid materials comprised of organized organic linkers and metal cations. They can display enormously high surface areas with tunable pore size and functionality, and can be used as hosts for a range of guest molecules. Since their discovery, MOFs have experienced widespread exploration for their applications in gas st...
متن کاملAn eight-connected metal organic framework based on Cu5 clusters: Synthesis, structure, magnetic and catalytic properties
A reaction of copper acetate, 5-nitroisophthalic acid in a water-methanol mixture under solvothermal condition results in a new metal-organic framework compound, [Cu5(μ3-OH)2(H2O)6{(NO2)-C6H3-(COO)2}4].5H2O, (1). The compound contains Cu5 pentameric cluster units connected by 5-nitro isophthalate (NIPA) moieties forming a CdCl2-like layer, which are further connected by another NIPA moiety form...
متن کاملSynthesis of CuO Nanoparticles and Study on their Catalytic Properties
In this research, CuO spherical-like nanoparticles were synthesized using the planetary ball mill method. The structure, particle size and morphology of the resulting CuO nanoparticles were characterized by XRD (X-ray diffraction), SEM (scanning electron microscopy) and SAXS (small-angle X-ray scattering) methods. The results of this investigation showed ...
متن کاملSynthesis of Nanostructured MnNiAPSO-34 Catalyst: Catalytic Properties and Performance
Silicoaluminophosphate (SAPO-34) molecular sieve doped with transition metals, Mn and Ni, with different molar ratios (Mn/Ni=0.33, 3) were investigated for their activity, selectivity and lifetime in biomethanol to olefins reaction. MnNiAPSO-34 nanostructured catalyst was synthesized by hydrothermal method and addition of metals was carried out by isomorphous substitution into the crystalline f...
متن کاملEffect of pore sizes on catalytic activities of arenetricarbonyl metal complexes constructed within Zr-based MOFs.
Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations and Advances
سال: 2014
ISSN: 2053-2733
DOI: 10.1107/s2053273314087397